Jian Li , Shuai-Bing Ma , De-Sheng Wei , Wan-Yi Lan , Ting-Ting Xu , Yu-Teng Zhang , Nan Lv , Shuang-Bao Li
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引用次数: 0
Abstract
Herein, a novel CF3-functionalized zirconium-based metal-organic tetrahedron (ZrT-(CF3)2) was constructed based on 2.5-bis(trifluoromethyl)terephthalic acid (H2BDC-(CF3)2) ligand and trinuclear zirconocene building unit. Notably, the single crystals of ZrT-(CF3)2 was obtained under traditional solvothermal condition, while the yield and purity could be further improved by the microwave-assisted solvothermal method. Subsequently, the adsorption performance of ZrT-(CF3)2 for salicylic acid (SA) emerging contaminant was systematically evaluated, indicating a maximum adsorption capacity of 99.91 mg/g under optimal conditions. Furthermore, a possible adsorption mechanism was proposed based on experimental results and DFT simulations.
期刊介绍：
Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.
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