Wenya Xiang, Guozhao Wang, Zhiying Zhao, Meiyan Cui and Zhangzhen He
{"title":"A new salt-inclusion compound CsCl·(VOSe2O5)4 showing nearly isolated spin-1/2 chain structure with a typical square lattice†","authors":"Wenya Xiang, Guozhao Wang, Zhiying Zhao, Meiyan Cui and Zhangzhen He","doi":"10.1039/D4CE00936C","DOIUrl":null,"url":null,"abstract":"<p >A new salt-inclusion compound CsCl·(VOSe<small><sub>2</sub></small>O<small><sub>5</sub></small>)<small><sub>4</sub></small> was synthesized by the hydrothermal method, showing a linear spin-1/2 chain structure composed of corner-sharing VO<small><sub>6</sub></small> octahedra along the <em>c</em>-axis, where such spin-chains are stacked into a regular square lattice on the <em>a</em>–<em>b</em> plane. Magnetic measurements confirm that the title compound does not possess a long-range magnetic ordering down to 2 K, but shows a typical paramagnetic behavior.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 45","pages":" 6392-6395"},"PeriodicalIF":2.6000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00936c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
A new salt-inclusion compound CsCl·(VOSe2O5)4 was synthesized by the hydrothermal method, showing a linear spin-1/2 chain structure composed of corner-sharing VO6 octahedra along the c-axis, where such spin-chains are stacked into a regular square lattice on the a–b plane. Magnetic measurements confirm that the title compound does not possess a long-range magnetic ordering down to 2 K, but shows a typical paramagnetic behavior.
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