Cover Feature: Chirality at Metal in a Linear [Ag(NHC)2]+ Complex: Stereogenic C−Ag−C Axis, Atropisomerism and Role of π-π Interactions (Chem. Eur. J. 64/2024)
Alvaro Polo, Lara Gutiérrez Merino, Ricardo Rodríguez, Pablo J. Sanz Miguel
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引用次数: 0
Abstract
A pioneering example of linear chirality-at-metal: The concept of metal-centered chirality is no longer limited to octahedral, tetrahedral and square-planar geometries. Our design induces the formation of a stereogenic C−Ag−C axis as a consequence of atropisomerism. More importantly, π–π interactions, both in solution and the solid state, are crucial in preserving the chiral information. More information can be found in the Research Article by P. J. Sanz Miguel and co-workers (DOI: 10.1002/chem.202403239).
金属线性手性的开创性实例：以金属为中心的手性概念不再局限于八面体、四面体和方形平面几何。我们的设计诱导形成了立体的 C-Ag-C 轴，这是异构的结果。更重要的是，溶液和固态中的π-π相互作用对于保留手性信息至关重要。更多信息，请参阅 P. J. Sanz Miguel 及其合作者的研究文章。Sanz Miguel 及其合作者的研究文章中（DOI: 10.1002/chem.202403239）。
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