Jianhua Yu, Andy Dinh, Xingxing Zhong, Xiaoyan Jiang, Xianhui Bu, Xiang Zhao
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引用次数: 0
Abstract
There has long been a pursuit for a metal-organic framework (MOF)-based adsorbent for various hydrocarbon separations. Herein, we utilized simple trimesic acid and 1,2,4-triazole, together with the heterometallic strategy to produce two quaternary MOFs with a kgm-type structure. The cooperative coordination allows the immobilization of metal clusters into the pore channels, creating an appropriate pore size and high density of open metal sites. The resulting material shows excellent C2H2/CO2 separation performance with good stability.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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