ChemPren: a new and economical technology for conversion of waste plastics to light olefins

IF 3.4 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Reaction Chemistry & Engineering Pub Date : 2024-10-07 DOI:10.1039/D4RE00354C
Anne Gaffney, Debtanu Maiti, Debasish Kuila and Gennaro Mafia
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Abstract

With the ever-increasing demand for plastics, sustainable recycling methods are key necessities. The current plastics industry can manage to recycle only 10% of the 400 million metric tons of plastic produced globally. Waste plastics, in the current infrastructure, land up mostly in landfills. Although a lot of research efforts have been spent on processing and recycling co-mingled mixed plastics, energy-efficient sustainable and scalable routes for plastic upcycling are still lacking. Catalytic valorization of waste plastic feedstock is one of the potential scalable routes for plastic upcycling. Silica-alumina based materials, and zeolites have shown a lot of promise. A major interest lies in restricting catalyst deactivation, and refining product selectivity and yield for such catalytic processes. This article highlights ChemPren technology as a clean energy solution to waste plastic recycling. Co-mingled, mixed plastic feedstock along with spray dried, attrition resistant, ZSM-5 containing catalysts is preprocessed with an extruder to form optimally sized particles and fed into a fluidized bed reactor for short contact times to produce selectively and in high yields ethylenes, propylenes and butylenes. This techno-economic perspective indicates that the ChemPren technology can produce propylene at $0.16 per lb, whereas the current selling price of virgin propylene is $0.54 per lb. This technology can serve as a platform for mixed plastic upcycling, with more advancements necessary in the form of robust and resilient catalysts and reactor operation strategies for tuning product selectivity.

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ChemPren:将废塑料转化为轻质烯烃的新型经济技术
随着塑料需求的不断增长,可持续的回收方法成为关键的必要条件。目前的塑料工业只能回收利用全球生产的 4 亿吨塑料中的 10%。在目前的基础设施中,废塑料大多被填埋。尽管在处理和回收共混混合塑料方面投入了大量研究力量,但仍缺乏高效节能、可持续和可扩展的塑料升级再循环途径。废塑料原料的催化增值是塑料升级再循环的潜在可扩展途径之一。二氧化硅-氧化铝基材料和沸石已显示出广阔的前景。限制催化剂失活、提高产品选择性和产量是此类催化工艺的主要关注点。本文重点介绍了作为废塑料回收清洁能源解决方案的 ChemPren 技术。将共混的混合塑料原料与喷雾干燥、耐损耗、含有 ZSM-5 的催化剂一起用挤出机预处理,形成最佳尺寸的颗粒,然后送入流化床反应器,在短时间内接触,选择性地生产出高产率的乙烯、丙烯和丁烯。从技术经济角度看,ChemPren 技术生产丙烯的价格为每磅 0.16 美元,而目前原生丙烯的售价为每磅 0.54 美元。这项技术可以作为混合塑料升级再循环的平台,但还需要在坚固耐用的催化剂和调整产品选择性的反应器操作策略方面取得更多进展。
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来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
期刊最新文献
Back cover Back cover Linear scaling relationships in homogeneous photoredox catalysis† Immobilization of cationic dye on photoluminescent hydroxyapatite particles through a citric acid bonding layer† ChemPren: a new and economical technology for conversion of waste plastics to light olefins
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