Production of biodegradable packaging film based on PLA/starch: optimization via response surface methodology

Abstract

Today, economic consumption of biodegradable polymers is significant in many applications. Thermoplastic starch (TPS) and polylactic acid (PLA) are two bio-based and biodegradable polymers that are increasingly being used to replace the petrochemical-based polymers. Adding TPS into a PLA matrix can also decrease material cost and increase its biodegradation rate. This work tested the printability of TPS/PLA films. For this purpose, TPS was first prepared by the addition of sorbitol and glycerol as softeners using an internal mixer at 140°C. Then, it was added to the PLA in internal mixer at 180°C. To analyse the data, design of the experiment was done according to Box–Behnken design (BBD) method for three variables in three levels by using Design-Expert software, which led to the preparation of 15 samples. Individual and interactive effects of wt% of PLA in TPS/PLA mixture, the wt% of starch in TPS, and the ratio of sorbitol to glycerol on the tensile properties, thermal properties and printing properties (optical density) were investigated. Solvent-based flexographic ink was applied to test printability of the films. It has been found that the PLA can be successfully printed with flexographic solvent inks to achieve a quality comparable to that of common packaging films.