Features of Polymer Modification in a Supercritical Carbon Dioxide Environment

IF 1.6 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series C Pub Date : 2024-09-29 DOI:10.1134/S181123822460023X
A. B. Solovieva, P. S. Timashev
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Abstract

Processes of polymer modification in a supercritical carbon dioxide environment leading to the production of new materials intended primarily for medicine, pharmacology, and conducting polymer systems are analyzed. The processes of polymer impregnation in a supercritical carbon dioxide environment with carbon nanotubes to produce heat- and electrically conductive polymer materials and the processes of polymer micronization used in the development of polymer–polymer composite materials are considered. The processes of obtaining aerogel materials based on polysaccharides (sodium alginate) for use as matrices for biocompatible heterogeneous catalytic systems, the processes of impregnation of thermoplastics with photochromic and luminescent compounds leading to the corresponding photoactive polymer materials, and the processes of immobilization in natural polysaccharide matrices of biologically active compounds allowing the production of prolonged medicinal products are described. Particular attention is paid to the features of graft copolymerization, which allows obtaining biocompatible products for additive technologies and completely nontoxic materials with high adhesion to cells.

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超临界二氧化碳环境中聚合物改性的特点
分析了在超临界二氧化碳环境下聚合物改性过程,从而生产出主要用于医学、药理学和导电聚合物系统的新材料。考虑了在超临界二氧化碳环境中用碳纳米管浸渍聚合物以生产导热和导电聚合物材料的工艺,以及用于开发聚合物-聚合物复合材料的聚合物微粉化工艺。此外,还介绍了以多糖(海藻酸钠)为基础的气凝胶材料作为生物相容性异相催化系统基质的制备过程、热塑性塑料与光致变色和发光化合物浸渍制备相应光活性聚合物材料的过程,以及将生物活性化合物固定在天然多糖基质中以生产长效医药产品的过程。特别关注的是接枝共聚的特点,它可以获得用于添加剂技术的生物兼容产品和对细胞具有高粘附性的完全无毒材料。
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来源期刊
Polymer Science, Series C
Polymer Science, Series C 工程技术-高分子科学
CiteScore
3.00
自引率
4.50%
发文量
21
审稿时长
>12 weeks
期刊介绍: Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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