{"title":"The Second Law of Thermodynamics and the Surface Characteristics of Dispersed Systems","authors":"Yu. K. Tovbin","doi":"10.1134/S0036024424702078","DOIUrl":null,"url":null,"abstract":"<p>An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"98 12","pages":"2823 - 2827"},"PeriodicalIF":0.7000,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424702078","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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