Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core – a donor–acceptor multi-redox system†

IF 2.7 3区 化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-09-02 Epub Date: 2024-11-13 DOI:10.1039/d4ob01755b
Jeppe Granhøj , Viktor Bliksted Roug Pedersen , Kurt V. Mikkelsen , Mogens Brøndsted Nielsen
{"title":"Extended tetrathiafulvalene with a pentaleno[1,2-b:4,5-b′]difluorene core – a donor–acceptor multi-redox system†","authors":"Jeppe Granhøj ,&nbsp;Viktor Bliksted Roug Pedersen ,&nbsp;Kurt V. Mikkelsen ,&nbsp;Mogens Brøndsted Nielsen","doi":"10.1039/d4ob01755b","DOIUrl":null,"url":null,"abstract":"<div><div>A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-<em>b</em>:4,5-<em>b</em>′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"22 47","pages":"Pages 9259-9265"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024009376","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/13 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

Abstract

A novel extended tetrathiafulvalene was prepared by introducing the large pentaleno[1,2-b:4,5-b′]difluorene as a central polycyclic aromatic hydrocarbon moiety. This compound behaved as a multi-redox system that could take reversibly six redox states (−1, 0, +1, +2, +3, +4). The compound exhibited strong absorptions in the visible region with an end-absorption almost reaching to 700 nm.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
具有五烯并[1,2-b:4,5-b']二芴核心的扩展四硫杂戊烯--一种供体-受体多重氧化还原系统。
通过引入大的五烯并[1,2-b:4,5-b']二芴作为中心多环芳烃分子,制备出了一种新型的扩展四硫富戊烯。该化合物是一个多氧化还原体系,可以可逆地呈现六种氧化还原状态(-1、0、+1、+2、+3、+4)。该化合物在可见光区域表现出很强的吸收能力,其末端吸收几乎达到 700 纳米。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
期刊最新文献
Water-soluble squaramide functionalised peptides for sulfate recognition in aqueous media. Cyclisations and hydrolysis of geranyl and farnesyl halides in water facilitated by ultrasound-induced emulsification. Chemoselective transfer hydrogenation of alkynoates enabled by Cu(I)-photosensitizer catalysis. SEAr-based reductive arylation of indoles with ketones: skeletal metamorphosis of ketones into aryl architectures. 4-Chloro-2H-chromene-3-carbaldehyde: a valid scaffold in organic synthesis and future molecules for healthcare and energy.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1