Understudied High-Pollution Band along Long Island’s South Coastline Caused by the Interaction of New York City Urban Plumes and a Stagnant Sea Breeze Front

IF 2.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ACS Earth and Space Chemistry Pub Date : 2024-11-05 DOI:10.1021/acsearthspacechem.4c00193
Jie Zhang*, Margaret J. Schwab, Tianyu Zhu, Alexandra Catena and James J. Schwab*, 
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Abstract

Recent observations have highlighted extreme ozone exceedances (exceeding 100 ppb) and significant surface ozone variability along Long Island’s south shore, driven by the interaction between New York City urban plumes and a stagnant sea breeze front. Despite this, detailed spatial distribution data and associated aerosol processing information have been lacking, reducing attention to this high-pollution phenomenon. In this study, mobile lab measurements captured three extreme high ozone events on August 21, September 4, and September 6, 2023. These events confirmed the presence of a high ozone band, extending from Jones Beach to Ponquogue Beach (80–90 km). High-resolution rapid refresh (HRRR) simulations indicate that the extreme ozone concentrations (near or exceeding 100 ppb) were confined to the shallow marine boundary layer with a height of about 20–40 m along the coastline, with notable increases in particle NH4NO3 levels. The three year temporary Heckscher State Park monitor site measurements on the south shore further suggest a possible increasing trend in high ozone conditions for the Long Island south shore. This polluted band poses significant health risks to local communities as well as beachgoers on hot, sunny days and presents an opportunity for research on marine-related aerosol processing. Our study underscores the need for expanded air quality monitoring and alert systems for Long Island’s south shore as well as further studies on the marine–urban interface based on this highly polluted band.

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纽约市城市烟羽和滞留海风前沿相互作用造成的长岛南海岸线高污染带研究不足
最近的观测结果表明,长岛南岸的臭氧极度超标(超过 100 ppb),而且地表臭氧变化很大,其原因是纽约市的城市烟羽与停滞的海风前沿相互作用。尽管如此,详细的空间分布数据和相关的气溶胶处理信息却一直缺乏,从而降低了人们对这一高污染现象的关注。在这项研究中,移动实验室测量捕捉到了 2023 年 8 月 21 日、9 月 4 日和 9 月 6 日的三次极端高臭氧事件。这些事件证实了高臭氧带的存在,该臭氧带从琼斯海滩延伸至庞库格海滩(80-90 公里)。高分辨率快速刷新(HRRR)模拟表明,极端臭氧浓度(接近或超过 100 ppb)仅限于沿海岸线高度约为 20-40 米的浅海洋边界层,颗粒物 NH4NO3 含量明显增加。在南岸的 Heckscher 州立公园临时监测点进行的三年测量进一步表明,长岛南岸的高臭氧状况可能呈上升趋势。在炎热的晴天,这一污染带会对当地社区和海滩游客的健康造成严重威胁,同时也为与海洋相关的气溶胶处理研究提供了机会。我们的研究强调,有必要扩大长岛南岸的空气质量监测和警报系统,并在这一高污染带的基础上对海洋-城市界面进行进一步研究。
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来源期刊
ACS Earth and Space Chemistry
ACS Earth and Space Chemistry Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
5.30
自引率
11.80%
发文量
249
期刊介绍: The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.
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