{"title":"Synthesis and Reactivity of Palladium Complexes Bearing Phosphino-Amidinate Ligands: O–H Bond Activation by Metal–Ligand Cooperation","authors":"Yuka Yamamoto, Tomoya Mommae, Tatsuya Fujimoto, Mitsuru Kondo and Naofumi Tsukada*, ","doi":"10.1021/acs.organomet.4c0042910.1021/acs.organomet.4c00429","DOIUrl":null,"url":null,"abstract":"<p >Phosphine ligands bearing amidine groups were designed for the synthesis of complexes in which a metal center and ligands cooperate. Several palladium amidinate complexes were synthesized from these ligands. The reaction of these complexes with various organic molecules containing an acidic OH group gave the palladium amidine complexes. In the reaction, the O–H bond was activated by metal–ligand cooperation (MLC).</p>","PeriodicalId":56,"journal":{"name":"Organometallics","volume":"43 22","pages":"2972–2980 2972–2980"},"PeriodicalIF":2.5000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organometallics","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.organomet.4c00429","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Phosphine ligands bearing amidine groups were designed for the synthesis of complexes in which a metal center and ligands cooperate. Several palladium amidinate complexes were synthesized from these ligands. The reaction of these complexes with various organic molecules containing an acidic OH group gave the palladium amidine complexes. In the reaction, the O–H bond was activated by metal–ligand cooperation (MLC).
期刊介绍：
Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.
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