Amplification of the Surface-Enhanced Raman Scattering Signal from a Monolayer of Organic Molecules in Sandwich Structures Containing Plasmonic Silver Nanoplates

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-11-15 DOI:10.1007/s10812-024-01814-9
P. O. Malakhovsky, A. A. Ramanenka, M. V. Artemyev
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Abstract

A novel technique was developed for the preparation of bilayer sandwich-type structures containing monolayers or laterally-oriented silver nanoplates electrostatically deposited onto thin polymer films. The surface-enhanced Raman scattering (SERS) signal of 4-mercaptobenzoic acid in the ligand layer of the silver nanoplates was found to depend on the surface concentration of the deposited silver nanoplates in the monolayer. A two-fold enhancement was found for the surface-enhanced Raman scattering signal of the analyte located in the gaps between the silver nanoplate monolayers compared to the signal from a single silver nanoplate monolayer with identical surface concentration of the analyte molecules.

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在含有等离子银纳米板的夹层结构中放大单层有机分子的表面增强拉曼散射信号
研究人员开发了一种新技术,用于制备双层夹层型结构,其中包含静电沉积在聚合物薄膜上的单层或横向银纳米板。研究发现,银纳米板配体层中 4-巯基苯甲酸的表面增强拉曼散射(SERS)信号取决于单层沉积银纳米板的表面浓度。与分析物分子表面浓度相同的单个银纳米板单层的信号相比,位于银纳米板单层间隙中的分析物的表面增强拉曼散射信号增强了两倍。
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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