Origin of fluids in the Araró-Simirao geothermal system, Central Mexico

IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Journal of Geochemical Exploration Pub Date : 2024-11-20 DOI:10.1016/j.gexplo.2024.107637
Isabel Pérez-Martínez , Ruth Esther Villanueva-Estrada , Claudio Inguaggiato , Mario Alberto Hernández-Hernández , Giovanni Sosa-Ceballos
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Abstract

The Araró-Simirao geothermal system is located in the eastern part of Cuitzeo Lake in Michoacán, Mexico. It is a liquid-dominated convective system featuring a high salinity, rapid discharge, and heat loss derived into a self-sealing process. The reservoir temperature is higher than 200 °C, associated with a fracture zone linked to the Araró-Simirao fault. Samples of thermal fluids (water and gases) were collected from springs, wells, a mud pool, and runoff water in the study area. The waters had temperatures ranging from 31 °C and 76 °C and near-neutral pH values. Three hydrogeochemical facies types were identified, Na+- Cl, Ca2+-Na+ - HCO3, and Na+ -HCO3, associated with deep thermal water, groundwater, and recently infiltrated water, respectively.
According to the stable isotopes systematics, a binary mixture of thermal water and groundwater was calculated at a proportion from 61 % to 80 % of the thermal component. In the mud pool sample, the chemical composition of bubbling gas is CO2-dominated, with a mostly magmatic origin according to the Rc/Ra (5.19), CO2/3He (4.12 × 109) ratios, and the isotopic composition of δ13C(CO2) (−8 ‰). The gases dissolved in waters are characterized by higher N2 and CO2 concentrations compared to the other gases, representing possible mixing processes between an end-member enriched in CO2 and the chemical composition of air-saturated water. Regarding helium isotopes, the gases are the result of mixing origins between crustal, atmospheric, and mantellic helium, and 3 groups were identified: 1) high contribution of mantle helium ranging from 21 to 66 % up to (Mud pool, LS07 and LS07A) 2) high contribution of crustal helium (LSA-02, LSA-08A, Araró) ranging from 55 to 80 % and 3) high contribution of atmospheric helium of 84 % (LSA-08). The δ13C(CO2) results show a primary interaction with magmatic environments and a slightly sedimentary origin. The origin of CO2, MORB-type, as well as other gases, may be similar to that in Los Azufres. However, these gases reach the surface through different vertical paths, resulting in varying fluid compositions. In the study area, the Araró-Simirao and Huigo faults would act as zones for these gas ascents from the degassing source (magma) at depth.
According to the estimates of the magma aging model, the age of the mud pool sample is estimated to be 2.7 × 106 ± 1.2 × 106 years, which is younger than the andesitic basement rocks. Additionally, there is evidence of a more recent 3He input in the sample. However, the Los Azufres geothermal system has a 3He input from rocks that are even younger (1.5 × 105 years). This suggests that Los Azufres may have a more recent 3He input than Araro-Simirao.
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墨西哥中部 Araró-Simirao 地热系统的流体来源
Araró-Simirao 地热系统位于墨西哥米却肯州的奎策奥湖东部。这是一个以液体为主的对流系统,其特点是盐度高、排泄快、热量损失源自自封过程。储层温度高于 200 °C,与 Araró-Simirao 断层相连的断裂带有关。从研究区域的泉水、水井、泥浆池和径流水中采集了热流体(水和气体)样本。这些水的温度在 31 °C 至 76 °C 之间,pH 值接近中性。根据稳定同位素系统学,可以计算出热能水和地下水的二元混合物,其中热能水所占比例为 61% 至 80%。根据 Rc/Ra (5.19)、CO2/3He (4.12 × 109)比值和 δ13C(CO2)(-8 ‰)同位素组成,泥浆池样本中的气泡气体化学成分以 CO2 为主,主要来源于岩浆。与其他气体相比,溶解在水体中的气体具有较高的 N2 和 CO2 浓度,这表明富含 CO2 的末端分子与空气饱和水体的化学成分之间可能存在混合过程。在氦同位素方面,这些气体是地壳氦、大气氦和地幔氦之间混合的结果,共分为三组:1)地幔氦含量高,从 21%到 66%不等(泥潭、LS07 和 LS07A);2)地壳氦含量高(LSA-02、LSA-08A 和 Araró),从 55%到 80%不等;3)大气氦含量高,达 84%(LSA-08)。δ13C(CO2)结果显示,主要是与岩浆环境的相互作用,略有沉积作用。MORB 型二氧化碳以及其他气体的来源可能与洛斯阿祖弗雷斯相似。不过,这些气体到达地表的垂直路径不同,导致流体成分各异。根据岩浆老化模型的估算,泥浆池样本的年龄估计为 2.7×106±1.2×106 年,比安山岩基底岩石年轻。此外,有证据表明该样本中的 3He 输入较新。然而,洛斯阿苏弗雷斯地热系统的 3He 输入来自更年轻的岩石(1.5 × 105 年)。这表明,洛斯阿祖弗雷斯地热系统的 3He 输入可能比阿拉罗-锡米拉奥地热系统的 3He 输入时间更短。
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来源期刊
Journal of Geochemical Exploration
Journal of Geochemical Exploration 地学-地球化学与地球物理
CiteScore
7.40
自引率
7.70%
发文量
148
审稿时长
8.1 months
期刊介绍: Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics. Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to: define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas. analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation. evaluate effects of historical mining activities on the surface environment. trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices. assess and quantify natural and technogenic radioactivity in the environment. determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis. assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches. Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.
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