Synthesis of 1,4-benzodioxepinones via electrochemical oxyselenenylation of 2-O-tethered alkenyl benzoic acid and diselenides

IF 1.5 4区 化学 Q3 CHEMISTRY, ORGANIC Tetrahedron Letters Pub Date : 2024-11-24 DOI:10.1016/j.tetlet.2024.155389
Junsheng Hou , Bingxin You , Ruiqi Lv , Xinxin Zhang , Hao Zhang , Qiang Liu
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Abstract

An efficient methodology for the synthesis of seven-membered benzodioxepinones has been developed via electrochemical oxyselenenylation of 2-O-tethered alkenyl benzoic acid and diselenides under an external oxidant-free condition at room temperature. The experimental evidence supports this transformation through a radical mechanism.

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来源期刊
Tetrahedron Letters
Tetrahedron Letters 化学-有机化学
CiteScore
3.50
自引率
5.60%
发文量
521
审稿时长
28 days
期刊介绍: Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.
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