Reduced Graphene Oxide Loaded with ZCF Magnetic Nanoparticles as a Promising Photocatalyst and Antibacterial Agent

IF 2.7 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Journal of Cluster Science Pub Date : 2024-11-28 DOI:10.1007/s10876-024-02718-6
Osama H. Abuzeyad, Ahmed M. El-Khawaga, Hesham Tantawy, Mohamed Gobara, Mohamed A. Elsayed
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Abstract

Due to waste, pollution, and unequal distribution of the world’s finite freshwater resources, there is currently a problem of water scarcity. Therefore, developing novel, affordable, and efficient techniques for water purification is essential. Here, the photo-assisted degradation of Methyl Orange dye (MO) under visible light and UV was achieved by using reduced graphene oxide (RGO) photocatalyst loaded with Zn0.5Cu0.5Fe2O4 (ZCF) called MRGO 20. Furthermore, all prepared samples were characterized by X-ray diffraction (XRD), fourier transformation infrared (FTIR), transmission electron microscope (TEM), vibrating sample magnetometer (VSM) and Raman analysis. After 40 minutes, the high photocatalytic efficacy effectively eliminated about 96 % of the 10 ppm MO using 20 mg of MRGO 20 NPs at pH 5 under Visible light irradiation. From the results, MRGO 20 demonstrated good performance stability after five cycles of photocatalytic degradation of MO dye. The shown performance of the generated samples in both visible and UV light may motivate further investigation into more potent photocatalysts for water filtering. MRGO 20 NPs nanocomposite displayed great activity against Gram-negative (E. coli) bacteria with a zone of inhibition (ZOI) mm value of 24.0 mm, and high biofilm inhibition of 94.3%. The produced samples’ observed efficacy in both UV and visible light may encourage continued research into more effective photocatalysts for the filtration of water and for biological applications.

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负载ZCF磁性纳米颗粒的氧化石墨烯作为一种有前途的光催化剂和抗菌剂
由于浪费、污染和世界上有限的淡水资源分配不均,目前存在着水资源短缺的问题。因此,开发新颖、经济、高效的水净化技术至关重要。本文采用负载Zn0.5Cu0.5Fe2O4 (ZCF)的还原性氧化石墨烯(RGO)光催化剂MRGO 20,实现了甲基橙染料(MO)在可见光和紫外下的光辅助降解。采用x射线衍射(XRD)、傅里叶变换红外(FTIR)、透射电子显微镜(TEM)、振动样品磁强计(VSM)和拉曼分析对制备的样品进行了表征。40分钟后,在可见光照射下,使用20 mg MRGO 20 NPs在pH 5下有效地去除约96%的10 ppm MO。结果表明,经过5次光催化降解MO染料后,MRGO 20表现出良好的性能稳定性。所生成的样品在可见光和紫外光下的表现可以激发对更有效的水过滤光催化剂的进一步研究。MRGO - 20nps纳米复合材料对革兰氏阴性(E. coli)细菌具有良好的抑制活性,其抑制区(ZOI) mm值为24.0 mm,生物膜抑制率为94.3%。所生产的样品在紫外线和可见光下观察到的功效可能会鼓励继续研究用于水过滤和生物应用的更有效的光催化剂。
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来源期刊
Journal of Cluster Science
Journal of Cluster Science 化学-无机化学与核化学
CiteScore
6.70
自引率
0.00%
发文量
166
审稿时长
3 months
期刊介绍: The journal publishes the following types of papers: (a) original and important research; (b) authoritative comprehensive reviews or short overviews of topics of current interest; (c) brief but urgent communications on new significant research; and (d) commentaries intended to foster the exchange of innovative or provocative ideas, and to encourage dialogue, amongst researchers working in different cluster disciplines.
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