Ye Rin Choi, Seongeun Kang, Junyeon Hwang, Hongchan An* and Ki Bum Hong*,
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引用次数: 0
Abstract
A mild and general method for photoredox-catalyzed trifluoromethylative and pentafluoroethylative heterofunctionalization of alkenes is proposed. In this reaction, the Togni reagent serves as a CF3- or CF2CF3-radical source for the regioselective formation of the C–CF3 and C–CF2CF3 bonds from alkenes, and additional nucleophiles (O, S, N) provide C–O, C–S, and C–N bonds, respectively. These reactions provide a common gateway to access the fluoroalkylative heterofunctionalization of alkenes.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍：
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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