Reference Correlations of the Viscosity and Thermal Conductivity of Acetone from the Triple Point to High Temperatures and Pressures

IF 2.5 4区 工程技术 Q3 CHEMISTRY, PHYSICAL International Journal of Thermophysics Pub Date : 2024-12-04 DOI:10.1007/s10765-024-03465-6
Sofia G. Sotiriadou, Eleftheria Ntonti, Marc J. Assael, Marcia L. Huber
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Abstract

This paper presents new wide-ranging correlations for the viscosity and thermal conductivity of acetone (2˗propanone or dimethyl ketone) based on critically evaluated experimental data. Both correlations are designed to be used with a Helmholtz-energy equation of state (EOS) that extends from the triple point to 550 K, at pressures up to 700 MPa. The viscosity correlation is valid from the triple point to 550 K and up to 162 MPa pressure, while the thermal conductivity is valid from the triple point to 550 K and 700 MPa. The estimated uncertainty (at a 95 % confidence level) for the viscosity varies from a low of 2 % for the low-pressure gas (p < 0.5 MPa) to 5.5 % for the liquid phase at pressures up to 162 MPa, and for thermal conductivity varies from a low of 3.5% for the low-pressure gas up to 6.2% for the thermal conductivity at pressures up to 700 MPa.

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丙酮的粘度和热导率从三相点到高温高压的参考相关性
本文基于严格评估的实验数据,提出了丙酮(丙酮或二甲基酮)的粘度和热导率之间新的广泛相关性。这两种相关性都设计用于从三相点延伸到550 K,压力高达700兆帕的亥姆霍兹能量状态方程(EOS)。从三相点到550 K和高达162 MPa的压力,粘度相关性是有效的,而热导率从三相点到550 K和700 MPa是有效的。粘度的估计不确定度(95%置信度)从低压气体(0.5 MPa)的2%到液相(162mpa)的5.5%不等,热导率从低压气体的3.5%到压力高达700mpa的6.2%不等。
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来源期刊
CiteScore
4.10
自引率
9.10%
发文量
179
审稿时长
5 months
期刊介绍: International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.
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