3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands

IF 1.1 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424700726
O. Yu. Trofimova, D. S. Kolevatov, N. O. Druzhkov, A. V. Maleeva, I. A. Yakushev, P. V. Dorovatovskii, A. V. Piskunov
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引用次数: 0

Abstract

New heteroleptic metal-organic frameworks (MOF) of zinc (3D MOF) and cadmium (2D MOF) are prepared by the two-stage synthesis: [Zn(pQ)(DPT)]·2DMF (I) and [Cd2(NO3)2-(pQ)(DPT)3]·2DMF·2MeOH (II), where pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, DPT is 3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine, and DMF is N,N-dimethylformamide (DMF). The structures of the compounds are studied by XRD (CIF files CCDC nos. 2332754 (I) and 2332755 (II)). The thermal stability of the MOF is studied by thermogravimetry.

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来源期刊
Russian Journal of Coordination Chemistry
Russian Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
2.40
自引率
15.80%
发文量
85
审稿时长
7.2 months
期刊介绍: Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
期刊最新文献
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