2,4-Di­chloro-6-{N-[2-(tri­fluoro­meth­yl)phen­yl]carboximido­yl}phenol

IUCrData Pub Date : 2024-11-01 Epub Date: 2024-11-14 DOI:10.1107/S2414314624010745
Zizipho Xantini , Alfred Muller , Koop Lammertsma
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Abstract

The title compound was synthesized by the condensation between tri­fluoro­methyl­aniline and di­chloro­salicyl­aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho­rhom­bic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol­ecules pack together to form a zigzag pattern along the c axis.
The title compound, C14H8Cl2F3NO, was synthesized by the condensation between tri­fluoro­methyl­aniline and di­chloro­salicyl­aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho­rhom­bic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol­ecules pack together to form a zigzag pattern along the c axis.
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——2,4-Di-chloro-6 N - [2 - (tri-fluoro-meth-yl) phen-yl] carboximido-yl phenol…….
标题化合物C14H8Cl2F3NO由三氟甲基苯胺与二氯水杨醛亲核加成缩合成半胺,脱水生成亚胺。该化合物在两个芳环之间形成一个二面角为44.70(5)°的正菱形Pbca (Z = 8)空间群。在晶体中,分子聚集在一起,沿着c轴形成之字形图案。
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