{"title":"3aH,4H,5H,8H,9H,9aH-Cycloocta[d][1,3]dioxole-2-thione","authors":"Dieter Schollmeyer , Claudia Kammler , Heiner Detert","doi":"10.1107/S2414314624010198","DOIUrl":null,"url":null,"abstract":"<div><div>The thionocarbonate of <em>trans</em>-cyclooctenediol, C<sub>9</sub>H<sub>12</sub>O<sub>2</sub>S, crystallizes with a 9/1 disorder in the position of the <em>R,R</em> and <em>S,S</em>-enantiomers. As a result of <em>trans</em>-annulation, both rings adopt a twist conformation.</div></div><div><div>The thionocarbonate of <em>trans</em>-cyclooctenediol, C<sub>9</sub>H<sub>12</sub>O<sub>2</sub>S, crystallizes with a 9/1 disorder in the position of the <em>R,R</em> and <em>S,S</em>-enantiomers. As a result of <em>trans</em>-annulation, both rings adopt a twist conformation.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (219KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 11","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618877/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S241431462400097X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The thionocarbonate of trans-cyclooctenediol, C9H12O2S, crystallizes with a 9/1 disorder in the position of the R,R and S,S-enantiomers. As a result of trans-annulation, both rings adopt a twist conformation.
The thionocarbonate of trans-cyclooctenediol, C9H12O2S, crystallizes with a 9/1 disorder in the position of the R,R and S,S-enantiomers. As a result of trans-annulation, both rings adopt a twist conformation.
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