4′-(2-Methoxyphenyl)-2,2′:6′,2′′-terpyridine

IUCrData Pub Date : 2024-11-01 DOI:10.1107/S241431462401143X

Eric M. Njogu , David O. Juma , Sizwe J. Zamisa , Bernard Omondi , Vincent O. Nyamori

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Abstract

In the title compound, the dihedral angles between the central pyridine ring and the peripheral rings are 22.24 (4) and 2.38 (4)°. In the crystal, pairwise C—H⋯N hydrogen bonds form inversion dimers described by an R²₂(6) graph set descriptor, which further interact through C—H⋯π and π–π interactions, creating a two-dimensional supramolecular network propagating in the bc plane.

In the title compound, C₂₂H₁₇N₃O, the N atoms of the pyridine rings exhibit a typical trans–trans arrangement: the dihedral angles between the central pyridine ring and the peripheral rings are 22.24 (4) and 2.38 (4)°. In the crystal, pairwise C—H⋯N hydrogen bonds form inversion dimers described by an R²₂(6) graph set descriptor, which further interact through C—H⋯π and π–π interactions, creating a two-dimensional supramolecular network propagating in the bc plane.

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4 ' - (2-Meth-oxy-phen-yl) 2、2’:6 ',2”-terpyridine。

在标题化合物c22h17n30o中，吡啶环的N原子呈典型的反式排列，中心吡啶环与外围吡啶环之间的二面角分别为22.24(4)°和2.38(4)°。在晶体中，一对C-H⋯N氢键形成由r22(6)图集描述符描述的反转二聚体，它们进一步通过C-H⋯π和π-π相互作用相互作用，形成在bc平面上传播的二维超分子网络。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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