Environmentally Stable Reversible Cavitand Molecular Switches Based on the Excimer of Perylene

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC Journal of Organic Chemistry Pub Date : 2024-12-11 DOI:10.1021/acs.joc.4c01196

Zhi Yu, Yixing He, Pan Liao, Selina X. Yao, Yuping Zhao, Wenjie Liang, Weiying Lin, Martin Saunders, Hai Xu

引用次数: 0

Abstract

Environmentally stable novel flexible bisperylene resorcin[4]arene molecular switch cavitand B and the corresponding rigid cavitand A were synthesized and a single crystal was obtained. Spectroscopic analysis revealed the formation of an excimer of perylene within the cavitand. The presence of flexible chains in cavitand B confers a high degree of environmental stability, rendering its fluorescence unaffected by external factors such as pH and temperature variations. In contrast, the rigid cavitand A exhibits heightened sensitivity to changes in environmental conditions.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.

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