Field emission performance of graphene-incorporated aluminum-based metal matrix composite†

IF 4.6 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanoscale Advances Pub Date : 2024-11-25 DOI:10.1039/D4NA00646A
Sunil Kumar Pradhan, Pandiyarajan K., Shubham Patil, Padmakar G. Chavan, Raphael Longuinhos Monteiro Lobato, Jenaina Ribeiro-Soares and Dattatray J. Late
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Abstract

The ‘close proximity’ configuration was used for field emission analysis of graphene-incorporated aluminum (Al) composites. The turn-on field was found to be 2 V μm−1 for the AlGr1 (1% graphene (by weight) inside the Al matrix) composite compared to 4.75 V μm−1 for the pristine aluminum sample. As the potential was increased, the current due to emission expeditiously increased in an electric field of 4 V μm−1, with 1 mA cm−2 current density due to emission for the AlGr1 composite, compared to that of 1.08 μA cm−2 for Al. The turn-on value was visually perceived to be superior for the AlGr1 composite as compared to the value for Al. Also, a quite stable emission current was recorded for the AlGr1 composite as compared to Al. Furthermore, the composites maintained approximately 98.7% of the density of pure aluminum following the sintering process. The structural wholeness and the nonexistent porous quality of the sintered specimens was confirmed via X-ray micro-computed tomography (micro-CT). The thermal amalgamation of the AlGr composite materials at 640 °C was found to be adequate, and produced composites with the desired strength. These evaluations indicate that AlGr composites can be excellently applied as cathodes and for the prevention of crumpling of electrical line cables.

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石墨烯掺杂铝基金属基复合材料的场发射性能。
“近距离”配置用于石墨烯铝复合材料的场发射分析。与原始铝样品的4.75 V μm-1相比,AlGr1 (Al基体中含有1%石墨烯)复合材料的导通场为2 V μm-1。随着电位的增加,在4 V μm-1的电场中,发射电流迅速增大,与Al的1.08 μA cm-2相比,AlGr1复合材料的发射电流密度为1 mA cm-2。从视觉上看,AlGr1复合材料的导通值优于Al,并且与Al相比,AlGr1复合材料的发射电流相当稳定。在烧结过程中,复合材料的密度保持在纯铝的98.7%左右。通过x射线显微计算机断层扫描(micro-CT)证实了烧结试样的结构完整,不存在多孔性。结果表明,在640℃的温度下,alcr复合材料的热熔合效果良好,复合材料的强度达到了要求。这些评价表明,AlGr复合材料可以很好地应用于阴极和防止电缆皱缩。
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来源期刊
Nanoscale Advances
Nanoscale Advances Multiple-
CiteScore
8.00
自引率
2.10%
发文量
461
审稿时长
9 weeks
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