Probing the difference in improving the ignition and combustion of micro/nano-sized aluminum powder modified by VitonA

IF 3.9 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science Pub Date : 2024-12-07 DOI:10.1007/s10853-024-10486-x
Yang Chen, Jiquan Wang, Yanan Wang, Baozhong Zhu, Yunlan Sun
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Abstract

Aluminum (Al) powder is commonly used in solid propellants because of its high energy density. However, Al powder is prone to agglomeration during combustion, resulting in lower combustion efficiency. The energy-containing composites of micro/nano-sized Al powder modified by the hexafluoropropylene and vinylidene fluoride dipolymers (VitonA) were fabricated by an evaporation solvent method, and the morphology, thermal behavior, and ignition and combustion (IAC) properties were investigated. The IAC performance of the nano-sized aluminum (nAl) is improved obviously when the coating concentration of VitonA reaches 15%, and higher combustion intensity is attained, which confirms the occurrence of the preignition reaction between nAl and fluoropolymer. Although the IAC properties of micro-sized Al (μAl) powder are also improved by VitonA, there is different impact mechanism of VitonA on the nAl and μAl. These results provide guidance for inhibiting the agglomeration of Al powder and improving its combustion efficiency.

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探讨VitonA改性微纳铝粉在改善着火燃烧性能方面的差异
铝粉因其高能量密度而被广泛用于固体推进剂中。但铝粉在燃烧过程中容易结块,导致燃烧效率较低。采用蒸发溶剂法制备了六氟丙烯和偏氟乙烯二聚体(VitonA)改性的微纳米铝粉含能复合材料,并对其形貌、热行为和着火燃烧性能进行了研究。当VitonA涂层浓度达到15%时,纳米铝(nAl)的IAC性能得到明显改善,燃烧强度更高,证实了nAl与含氟聚合物之间存在预燃反应。虽然VitonA也能提高微Al (μAl)粉末的IAC性能,但VitonA对nAl和μAl的影响机制不同。研究结果对抑制铝粉的结块,提高其燃烧效率具有指导意义。图形抽象
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阿拉丁
N, N-dimethylformamide (DMF)
阿拉丁
n-hexane
阿拉丁
VitonA
阿拉丁
N, N-dimethylformamide (DMF)
阿拉丁
n-hexane
阿拉丁
VitonA
阿拉丁
N, N-dimethylformamide (DMF)
阿拉丁
n-hexane
阿拉丁
VitonA
来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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