Fiber Sorbents – A Versatile Platform for Sorption-Based Gas Separations

IF 14 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of materials research Pub Date : 2024-12-12 DOI:10.1021/accountsmr.4c00201
João Marreiros, Yuxiang Wang, MinGyu Song, William J. Koros, Matthew J. Realff, Christopher W. Jones, Ryan P. Lively
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Abstract

Increasing demand for high-purity fine chemicals and a drive for process intensification of large-scale separations have driven significant work on the development of highly engineered porous materials with promise for sorption-based separations. While sorptive separations in porous materials offer energy-efficient alternatives to longstanding thermal-based methods, the particulate nature of many of these sorbents has sometimes limited their large-scale deployment in high-throughput applications such as gas separations, for which the necessary high feed flow rates and gas velocities accrue prohibitive operational costs.

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对高纯度精细化学品的需求不断增长,以及大规模分离过程的不断强化,推动了大量工作的开展,开发出有望用于吸附分离的高工程多孔材料。虽然多孔材料中的吸附分离为长期以来基于热的方法提供了节能的替代品,但许多此类吸附剂的微粒性质有时限制了它们在气体分离等高通量应用中的大规模应用,因为在这些应用中,必要的高进料流速和气体速度会产生令人望而却步的操作成本。
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