Extraction Separation of Molybdenum by Means of CYANEX®600 from Solutions for Nitric Acid Leaching of Industrial Products

IF 0.7 4区 工程技术 Q4 ENGINEERING, CHEMICAL Theoretical Foundations of Chemical Engineering Pub Date : 2024-12-16 DOI:10.1134/S0040579524700271
L. M. Karimova, T. O. Oleinikova, I. V. Terent’eva
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Abstract

The extraction of molybdenum from a multicomponent nitric acid productive solution with various values of the redox potential using extractant CYANEX®600 (Solvay company) and diluent Elixore 205 (Total company) is studied. Extraction curves are constructed and the process of molybdenum extraction from nitrate leaching solutions is simulated using the Minchem software package from Solvay. The number of extraction stages necessary to achieve an extraction efficiency of more than 95% is selected, which is found to be equal to two stages with phase ratios (Org/Aq) of 1.5 : 1 and 1 : 1 for an extractant concentration of 25%. It is established that the degree of extraction of molybdenum at the extraction stages with reduced values of the redox potential of the productive solution increases from 68.64 to 97.36%.

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用CYANEX®600从工业产品的硝酸浸出溶液中提取分离钼
研究了使用萃取剂 CYANEX®600 (苏威公司)和稀释剂 Elixore 205(道达尔公司)从具有不同氧化还原电位值的多组分硝酸生产溶液中萃取钼的过程。利用索尔维公司的 Minchem 软件包构建了萃取曲线,并模拟了从硝酸盐浸出液中萃取钼的过程。选定了萃取效率达到 95% 以上所需的萃取阶段数,发现在萃取剂浓度为 25% 时,萃取阶段数等于两个阶段,相比(Org/Aq)分别为 1.5 : 1 和 1 : 1。在生产溶液氧化还原电位值降低的萃取阶段,钼的萃取率从 68.64% 提高到 97.36%。
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来源期刊
CiteScore
1.20
自引率
25.00%
发文量
70
审稿时长
24 months
期刊介绍: Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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