Surface Tension of Arsenic Acid Solutions

IF 0.7 4区 工程技术 Q4 ENGINEERING, CHEMICAL Theoretical Foundations of Chemical Engineering Pub Date : 2024-12-16 DOI:10.1134/S0040579524700076
T. K. Menshchikova, K. S. Nikonov, M. N. Brekhovskikh, L. A. Vaimugin, O. E. Myslitskii
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Abstract

Investigation of the physicochemical properties of the H3AsO4–H2O system is of great importance, since arsenic acid is involved in the electrochemical synthesis of arsine, which is used to produce AIIIBV semiconductors. The surface tension of arsenic acid solutions of various concentrations in a wide temperature range (20–80°C) was measured by the stalagmometric method. It has been determined that arsenic acid in an aqueous solution is a surface-inactive substance because, with increasing concentration of H3AsO4 in solution, its surface tension increases.

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砷酸溶液的表面张力
研究H3AsO4-H2O体系的物理化学性质是非常重要的,因为砷酸参与了用于生产AIIIBV半导体的arsine的电化学合成。用石笋法测定了不同浓度的砷酸溶液在20 ~ 80℃宽温度范围内的表面张力。在水溶液中砷酸是一种表面无活性物质,因为随着溶液中H3AsO4浓度的增加,其表面张力增大。
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来源期刊
CiteScore
1.20
自引率
25.00%
发文量
70
审稿时长
24 months
期刊介绍: Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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