Environment-Friendly Lead-Free Cs3Bi2Br9 Perovskite Quantum Dots as Fluorescent Probes for Rapid Detection of Oxytetracycline Via Inner Filter Effect

Abstract

All-inorganic perovskite quantum dots have sparked a research boom due to their excellent optical properties, however, their own strong ionicity and lead toxicity have hindered further development in the field of sensing. In this study, we have solved the toxicity problem of lead-based perovskite quantum dots by replacing lead with green metal bismuth. Meanwhile, due to the ligand-passivation effect of oleylamine and oleic acid, we successfully synthesized highly stable bismuth-based perovskite quantum dots(Cs₃Bi₂Br₉ PQDs)in ethanol, and constructed the environment-friendly fluorescence sensor for the quantitative detection of oxytetracycline (OTC) for the first time. The results demonstrated that the fluorescence quenching degree of Cs₃Bi₂Br₉ PQDs showed a good linear relationship with the concentration of OTC within the range of 2.0 ~ 18 µM, and the detection limit was 0.432 µM. By studying fluorescence lifetime, absorption spectroscopy, and evaluation of internal filtration parameters, it was proved that the sensing mechanism was caused by the inner filter effect owing to the overlapping of fluorescence emission spectrum of Cs₃Bi₂Br₉ PQDs and UV absorption spectrum of OTC. Moreover, Cs₃Bi₂Br₉ PQDs fluorescent sensor had good selectivity and anti-interference ability. It is believed that this work will open up a new way for lead-free perovskite quantum dots fluorescence sensor in the field of analytical detection.