Metallic sealants increase flux and change selectivity in supported molten-salt membranes.

IF 3.4 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Reaction Chemistry & Engineering Pub Date : 2024-12-03 DOI:10.1039/d4re00449c
Liam A McNeil, Guannan Chen, Wenting Hu, Evangelos I Papaioannou, Ian S Metcalfe, Greg A Mutch
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Abstract

Metallic sealants are widely used with high-temperature membranes. Here we show that their use in supported molten-salt membranes results in order-of-magnitude differences in CO2 flux and introduces O2 co-permeation. The 'short-circuiting' effect they introduce has important implications for the design of future experiments, and the interpretation of past work.

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金属密封剂广泛用于高温膜。在这里,我们展示了在支撑熔盐膜中使用金属密封剂会导致二氧化碳通量的数量级差异,并引入氧气共渗。它们引入的 "短路 "效应对未来实验的设计和过去工作的解释具有重要影响。
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来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
期刊最新文献
Back cover Ultrasound-assisted condensation cyclization reaction: fast synthesis of quinazolinones from o-aminobenzamides and aldehydes under ambient conditions† Metallic sealants increase flux and change selectivity in supported molten-salt membranes. Monitoring and controlling zeolite synthesis via reactor-based solutions: a fed-batch strategy. Back cover
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