Haoran Li, Minyao Kuang, Yuwei Liu, Wei Yi, Shengdong Wang
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引用次数: 0
Abstract
Environmentally benign calcium(II) triflimide has emerged as a sustainable substitute for transition-metal catalysts, rare-earth metals, and strong Brønsted acids in promoting organic synthesis, thereby attracting considerable attention. Recently, elegant methodologies involving calcium(II) triflimide have been developed, such as cyclizations, dehydrative functionalizations, hydroarylation reactions, hydrofunctionalizations, reductions, rearrangements, and novel selenylations, hese have been applied to a diverse range of substrates inculding alcohols, alkenes, alkynes, carbonyl compounds, imines, N,O-acetals, and selenides for the formation of C–C or C–X bond. This review provides a comprehensive and detailed overview of the recent progress in the application of calcium(II) triflimideas as an organic synthesis catalyst, summarizing the crucial achievements in reaction methodologies and the plausible reaction mechanisms.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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