Structure and Properties of Hybrid Composites Based on Dressed Aluminosilicate Microspheres and Polypropylene Graft Copolymer with Methacrylic Acid

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED Russian Journal of Applied Chemistry Pub Date : 2024-12-18 DOI:10.1134/S1070427224050057
N. T. Kakhramanov, R. V. Kurbanova
{"title":"Structure and Properties of Hybrid Composites Based on Dressed Aluminosilicate Microspheres and Polypropylene Graft Copolymer with Methacrylic Acid","authors":"N. T. Kakhramanov,&nbsp;R. V. Kurbanova","doi":"10.1134/S1070427224050057","DOIUrl":null,"url":null,"abstract":"<p>The paper presents the results of a study of the influence of the dressing process of a hollow aluminosilicate microsphere on the structural features and regulaties of changes in the main physical and mechanical characteristics of composites based on polypropylene graft copolymer with methacrylic acid. Organosilicon compound АГМ-9 (γ-aminopropyltriethoxysilane) was used as a dressing size. The mechanism of the sol-gel reaction in the process of dressing the surface of microspheres is given. The introduction of dressed microspheres into the composition of the graft copolymer made it possible to obtain hybrid composites with improved physical and mechanical properties. The most probable mechanism for the formation of the structure of hybrid composites with the formation of a three-level cross-linked spatial structure - “interpenetrating networks” is considered. The use of the method of thermomechanical studies of dressed and undressed composites confirmed the assumption of the formation of interpenetrating networks.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":"97 5","pages":"484 - 492"},"PeriodicalIF":0.6000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070427224050057","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0

Abstract

The paper presents the results of a study of the influence of the dressing process of a hollow aluminosilicate microsphere on the structural features and regulaties of changes in the main physical and mechanical characteristics of composites based on polypropylene graft copolymer with methacrylic acid. Organosilicon compound АГМ-9 (γ-aminopropyltriethoxysilane) was used as a dressing size. The mechanism of the sol-gel reaction in the process of dressing the surface of microspheres is given. The introduction of dressed microspheres into the composition of the graft copolymer made it possible to obtain hybrid composites with improved physical and mechanical properties. The most probable mechanism for the formation of the structure of hybrid composites with the formation of a three-level cross-linked spatial structure - “interpenetrating networks” is considered. The use of the method of thermomechanical studies of dressed and undressed composites confirmed the assumption of the formation of interpenetrating networks.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
基于压制硅酸铝微球和聚丙烯与甲基丙烯酸接枝共聚物的混合复合材料的结构与性能
本文介绍了中空硅酸铝微球敷料工艺对基于聚丙烯与甲基丙烯酸接枝共聚物的复合材料的结构特征和主要物理机械特性变化的影响的研究结果。有机硅化合物АГМ-9(γ-氨基丙基三乙氧基硅烷)被用作敷料。给出了微球表面敷料过程中溶胶-凝胶反应的机理。在接枝共聚物的成分中引入敷料微球,可以获得物理和机械性能更好的混合复合材料。研究考虑了形成三级交联空间结构--"互穿网络 "的混合复合材料结构的最可能的形成机制。使用热力学方法对包扎和未包扎的复合材料进行研究,证实了形成互穿网络的假设。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
期刊最新文献
Hydrothermally Engineered Covellite (CuS) Nanoplates with Superior Chemocatalytic and Photocatalytic Responses Effect of Graphite Properties on Reversible Capacitance and Coulomb Efficiency Depolymerization of Polyolefins by Ethenolysis Reaction: a Feasibility Study Using a Model Polyoctenamer Synthesis of Bis(hydroxymethyl) 1,4-Disubstituted 1,2,3-Triazoles Derivatives Influence of Low-Temperature Underwater Plasma Parameters on the Phase Composition of Copper Oxides
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1