From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes

IF 4.6 1区 化学 Q1 CHEMISTRY, ORGANIC Organic Chemistry Frontiers Pub Date : 2024-12-19 DOI:10.1039/d4qo02143f
Balázs Tóth, Stephanie Grace Elizabeth Amos, Arjan Willem Kleij
{"title":"From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes","authors":"Balázs Tóth, Stephanie Grace Elizabeth Amos, Arjan Willem Kleij","doi":"10.1039/d4qo02143f","DOIUrl":null,"url":null,"abstract":"Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene-yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon-carbon bond formation and beyond.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":"27 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo02143f","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0

Abstract

Metal-catalyzed reductive coupling reactions between alkenes and alkynes are a long-standing tradition as a way to create complex unsaturated building blocks of value in organic synthesis ventures. Here, we review the general synthetic approaches realized under Co-catalysis utilizing chemical reductants, albeit with some limitations in scope and user-friendliness. A more recent advancement shows that these reductive ene-yne coupling reactions can also be accommodated by photoredox catalysis marking a stepping stone in the area, and creating new incentives for this kind of carbon-carbon bond formation and beyond.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
求助全文
约1分钟内获得全文 去求助
来源期刊
Organic Chemistry Frontiers
Organic Chemistry Frontiers CHEMISTRY, ORGANIC-
CiteScore
7.90
自引率
11.10%
发文量
686
审稿时长
1 months
期刊介绍: Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
期刊最新文献
Palladium-Catalyzed Decarboxylative Domino Synthesis of Fused Quinolin-2(1H)-one Scaffolds Containing Perfluoroalkyl Unit Synthesis and Antibacterial Evaluation of Prenylacridone Alkaloids and Analogues A Persistent Concealed Non-Kekulé Nanographene: Synthesis and in-situ Characterization Solvent-dependent fluorescence sensing of Cu2+, Hg2+, and CN‒ based on thiosemicarbazone-functionalized pillar[5]arene and its applications in actual water samples and molecular logic gates From conventional to dual Co/photoredox mediated reductive coupling of alkynes and alkenes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1