Transparent, Fluorophore-Doped Cellulose Nanocrystal Films Prepared from Crop Residue: Superior Radiative Cooler and Organic Photodetector

IF 7.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-20 DOI:10.1021/acssuschemeng.4c08984
Utsav Mishra, Md. Arman Ansari, Akash Chaurasiya, Abhishek Kumar Singh, Debashis Panda
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Abstract

Carbon-neutral nanomaterials derived from lignocellulosic biomass remain the most preferred choice for lowering down the fossil-fuel-based energy consumption for indoor cooling and metal mining purposes. In this work, the synthetic methodologies for yielding a transparent, conducting cellulose nanocrystal (CNC) film from a highly abundant crop residue, rice straw (Oryza sp. Stems), have been presented. The self-assembly of CNC generates a predominant structural green color. Even the encapsulation of organic fluorophores in CNC films retains a chiral nematic order and a photonic band gap. The highly crystalline nature of the hydroxyl groups present in CNC regulates the excited-state dynamics of Rhodamine B encapsulated in the film. Nevertheless, the transreflective property of the CNC film has been demonstrated owing to its low solar light absorption and high mid-infrared (MIR) emissivity at the atmospheric transmission window (8–13 μm). The CNC film can bring down the temperature of the insulated box by ∼6 °C kept under solar simulator illumination, suggesting an effective radiative cooler. Further, the amine functionalization of CNC has resulted in a remarkable increase in current and mobility, improving the film’s conductivity by several folds. The photoresponsivity of the RhB-encapsulated-amine-functionalized CNC photodetector shows a peak response of ∼6.3 mA/W at ∼665 nm under zero bias. The external quantum efficiency of fabricated devices is about 1%. The CNC derived from the crop residue has multidimensional applications ranging from passive cooling to organic electronics.

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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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