Effect of Reduced Graphene Oxide Nanoparticles Added in Epoxy for Anticorrosion Coatings

Q3 Materials Science Macromolecular Symposia Pub Date : 2024-12-16 DOI:10.1002/masy.202400043
Ana L. Santos, Ygor M. de Paula, Maria P. Freire, Maria Costa
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Abstract

Corrosion is a natural phenomenon that affects many sectors that use metallic materials in their industrial plants, including the oil industry. In this sector, corrosion phenomena occur frequently in metal pipes, generating economic losses, environmental damage, and safety risks in general. The aim of this study is to evaluate the addition of laboratory-synthesized reduced graphene oxide (rGO) to an epoxy resin on the corrosion resistance of coatings for use in the oil sector. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, and scanning electron microscopy (SEM) analyses are carried out on the synthesized nanoparticles and on the nanocomposite coatings, which are prepared with 0.1–0.5 wt% of rGO. SEM analysis shows that there is a decrease in the number of defects on the surface of the samples as the concentration of rGO increases up to 0.3 wt%. The corrosion resistance of the coatings is evaluated by electrochemical impedance spectroscopy (EIS), which shows that the addition of rGO to the epoxy matrix improves corrosion protection compared to the pure coating, as it increases the diffusive path of the corrosive agents. The nanocomposite coating with 0.3 wt% rGO shows better anti-corrosion performance. This material can be applied both as an external and internal anti-corrosion coating in any industrial sector, as well as in the oil and gas industry.

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环氧树脂中加入还原氧化石墨烯纳米颗粒对防腐涂料的影响
腐蚀是一种自然现象,影响到包括石油工业在内的许多工业工厂中使用金属材料的部门。在该行业中,金属管道腐蚀现象频繁发生,造成经济损失、环境破坏和安全隐患。本研究的目的是评估将实验室合成的还原氧化石墨烯(rGO)添加到环氧树脂中,对石油行业涂料的耐腐蚀性的影响。采用x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、拉曼光谱(Raman)和扫描电镜(SEM)对合成的纳米颗粒和添加0.1 ~ 0.5 wt%还原氧化石墨烯制备的纳米复合涂层进行了分析。SEM分析表明,当还原氧化石墨烯浓度增加到0.3 wt%时,样品表面缺陷数量减少。通过电化学阻抗谱(EIS)对涂层的耐腐蚀性进行了评估,结果表明,与纯涂层相比,在环氧基体中添加还原氧化石墨烯增加了腐蚀剂的扩散路径,从而提高了涂层的防腐蚀能力。含有0.3 wt%还原氧化石墨烯的纳米复合涂层具有较好的防腐性能。这种材料既可以作为外部防腐涂层,也可以作为内部防腐涂层应用于任何工业领域,包括石油和天然气行业。
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来源期刊
Macromolecular Symposia
Macromolecular Symposia Materials Science-Polymers and Plastics
CiteScore
1.50
自引率
0.00%
发文量
226
期刊介绍: Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.
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