Rice Husk Filled PLA/PBAT Composites for Food Containers: Processability, Rheological and Thermal Properties

Q3 Materials Science Macromolecular Symposia Pub Date : 2024-12-16 DOI:10.1002/masy.202400093
Nicole Bohm Agostini, Vanessa Zimmer Kieffer, Ruth Marlene Campomanes Santana
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Abstract

This study explores the potential of using a composite material made of polylactic acid (PLA), polybutylene adipate-co-terephthalate (PBAT), and rice husk (RH) as an alternative for food containers. Two blends with 10 wt%–20 wt% of PBAT and four composites with 10 wt%–20 wt% of RH reinforcement are evaluated. The composite is created using an internal mixer and is analyzed using torque vs time mixing curves, melt flow index (MFI), thermogravimetric analysis, and differential scanning calorimetry (DSC). The blends exhibit higher crystallinity and superior mechanical properties compared to composites. Adding RH improves sustainability and decreases costs by utilizing agricultural waste but reduces flexural strength. However, the addition of PBAT increases flexibility, making it suitable for pliable material applications. The composite CO4 with 20 wt% of PBAT and RH demonstrates balanced performance in terms of lower MFI, thermal stability, and flexural strength, making it suitable for food tray applications. Further studies are needed to optimize the mechanical and barrier properties of these composites for specific applications.

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食品容器用稻壳填充PLA/PBAT复合材料:加工性、流变性和热性能
本研究探索了使用由聚乳酸(PLA)、聚己二酸丁二酯-对苯二甲酸酯(PBAT)和稻壳(RH)制成的复合材料作为食品容器替代品的潜力。评估了两种含10 wt% -20 wt% PBAT的共混物和四种含10 wt% -20 wt% RH增强的复合材料。该复合材料使用内部混合器创建,并使用扭矩与时间混合曲线,熔体流动指数(MFI),热重分析和差示扫描量热法(DSC)进行分析。与复合材料相比,共混物具有更高的结晶度和优越的机械性能。添加RH提高了可持续性,并通过利用农业废弃物降低了成本,但降低了弯曲强度。然而,PBAT的加入增加了灵活性,使其适用于柔韧材料的应用。含有20% PBAT和RH的CO4复合材料在较低的MFI,热稳定性和弯曲强度方面表现出平衡的性能,使其适用于食品托盘应用。需要进一步的研究来优化这些复合材料的机械和屏障性能,以适应特定的应用。
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来源期刊
Macromolecular Symposia
Macromolecular Symposia Materials Science-Polymers and Plastics
CiteScore
1.50
自引率
0.00%
发文量
226
期刊介绍: Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.
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