Effect of polyphenylene sulfide content on the properties of injection molding bonded NdFeB magnets Auswirkung des Polyphenylsulfid-Gehaltes auf die Eigenschaften von spritzgegossenen NdFeB-Magneten

Abstract

The effect of polyphenylene sulfide binder content on the properties of injection molding polyphenylene sulfide/NdFeB magnets were investigated. The maximum filling amount of NdFeB magnetic powder was 87.6 wt.-%, and the mixing process and subsequent injection molding of the polyphenylene sulfide/NdFeB were in good condition. The melt mass-flow rate of the polyphenylene sulfide/NdFeB granular materials reached 121.7 g/10 min, the compressive strength of the polyphenylene sulfide/NdFeB magnet was 92.18 MPa, and its maximum magnetic energy product reached 5.59 MGOe. The structure and morphology characteristics of polyphenylene sulfide/NdFeB magnets were investigated using scanning electron microscopy and atomic force microscopy. The corrosion behavior of polyphenylene sulfide/NdFeB magnets was also studied using potentiodynamic polarization curves and electrochemical impedance spectroscopy. The results indicated that the injection molding process facilitated the uniform coating of polyphenylene sulfide particles on NdFeB powder, which directly enhanced the corrosion resistance of polyphenylene sulfide/NdFeB magnets. With an increase in polyphenylene sulfide content, the surface of polyphenylene sulfide/NdFeB magnets became more uniform. The corrosion current density of 13 wt.-% polyphenylene sulfide/NdFeB magnet was approximately one order of magnitude lower than that of 9 wt.-% polyphenylene sulfide/NdFeB magnet, indicating an improved corrosion resistance of polyphenylene sulfide/NdFeB magnet.