{"title":"Synthesis and Characterization of Diarylgermanethione and Diarylgermaneselenone","authors":"Yizhen Chen, Gengwen Tan","doi":"10.1002/ejic.202400390","DOIUrl":null,"url":null,"abstract":"<p>Lewis acid/base-free diarylgermanethione <b>3</b> and diarylgermaneselenone <b>4</b> were synthesized through reactions of a heteroleptic diarylgermylene with elemental sulfur and selenium, respectively. They were fully characterized by structural, spectroscopic and computational methods. Germanethione underwent 1,2-addition with AlMe<sub>3</sub> at the Ge=S double to give Ge(IV) compound <b>5</b>. The chalcogen atoms in <b>3</b> and <b>4</b> could coordinate to copper halide to yield Cu(I) complexes <b>6</b> and <b>7</b>, respectively.</p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"27 34","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202400390","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Lewis acid/base-free diarylgermanethione 3 and diarylgermaneselenone 4 were synthesized through reactions of a heteroleptic diarylgermylene with elemental sulfur and selenium, respectively. They were fully characterized by structural, spectroscopic and computational methods. Germanethione underwent 1,2-addition with AlMe3 at the Ge=S double to give Ge(IV) compound 5. The chalcogen atoms in 3 and 4 could coordinate to copper halide to yield Cu(I) complexes 6 and 7, respectively.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
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