Maurice Franke, Lukas Stratmann, Yury V. Vishnevskiy, Beate Neumann, Hans-Georg Stammler, Norbert W. Mitzel
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引用次数: 0
Abstract
A tridentate trimethylstannyl substituted alkyne based on the tribenzotriquinacene (TBTQ) scaffold has been transformed into several gold(I)phosphane complexes by tin-gold exchange. While the molecular structures of the gold(I) derivatives with less bulky trimethyl and dimethylphenylphosphane ligands exhibit intermolecular aurophilic interactions, the sterically demanding triphenylphosphane ligands inhibit the occurrence of Au⋅⋅⋅Au contacts. In addition, a hexanuclear gold(I) system was synthesised by terminal functionalisation of the hexaalkynyl TBTQ. Investigations of the photophysical properties of the gold(I)phosphane TBTQ compounds revealed their luminescent character at room temperature.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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