Cationic Control of the Formation of Europium Carbodiimide Chlorides

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2024-10-17 DOI:10.1002/ejic.202400437

Dr. Oleksandr Kysliak, Dr. Markus Ströbele, Dr. David Enseling, Dr. Thomas Jüstel, Dr. H.-Jürgen Meyer

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Abstract

The solid-state syntheses and the structures of three new europium carbodiimide chlorides are reported: Eu₄(NCN)₃Cl₃=Eu⁽³⁺⁾Eu₃⁽²⁺⁾(NCN)₃Cl₃ (1), LiEu₂(NCN)Cl₃ (2) and Na₂Eu₁₄(NCN)₃Cl₂₄ (3). 1 is the second example of mixed-valent rare-earth carbodiimide after Eu₄F₅(NCN)₂. 2 belongs to a group of mixed carbodiimide compounds related to the Bideauxite group. 3 being the first Na-containing rare-earth carbodiimide. Syntheses in the field of rare-earth carbodiimides benefit from the usage of different alkali carbodiimides to direct reaction pathway into individual compounds. High-yield syntheses of 1–3, their crystal structures, and the photoluminescence properties of 3 are reported.

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阳离子控制碳二亚胺氯化铕的形成

本文报道了三种新型铕碳二亚胺氯化物的固态合成和结构：Eu4(NCN)3Cl3=Eu(3+)Eu3(2+)(NCN)3Cl3 (1), LiEu2(NCN)Cl3(2)和Na2Eu14(NCN)3Cl24(3)。1是继Eu4F5(NCN)2之后第二个混合价稀土碳二亚胺的例子。2属于一类与璧辉土族有关的混合碳二亚胺化合物。3是第一个含na的稀土碳二亚胺。稀土碳二亚胺的合成得益于使用不同的碱碳二亚胺直接反应生成单个化合物。报道了1-3的高产率合成、晶体结构和3的光致发光性质。

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.