1-Eth­oxy-3-[4-(eth­oxy­carbon­yl)phen­yl]-3-hy­droxy-1-oxopropan-2-aminium chloride

IUCrData Pub Date : 2024-10-01 Epub Date: 2024-10-31 DOI:10.1107/S2414314624010320
Dieter Schollmeyer , Igor Proz , Heiner Detert
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Abstract

The title compound was prepared as a racemate of R,R- and S,S-enanti­omers by reduction of the corresponding hy­droxy­imino­ketone. In the crystal, layers are formed via hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected via inter­digitated benzoic ester groups.
The title compound, C14H20NO5+·Cl, was prepared as a racemate of R,R- and S,S-enanti­omers by reduction of the corresponding hy­droxy­imino­ketone. In the crystal, layers are formed via hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected via inter­digitated benzoic ester groups.
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1-Eth-oxy-3 - [4 - (eth-oxy-carbon-yl) phen-yl] 3-hy-droxy-1-oxopropan-2-aminium氯。
标题化合物C14H20NO5 +·Cl-通过还原相应的羟基亚胺酮得到R,R-和S,S-对映体的外消旋体。在晶体中,通过四个铵基与氯离子的氢桥形成层;这些薄片通过指间苯甲酸酯基团连接。
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Re-refinement of dineodymium tris-[sulfate-(VI)] tetra-hydrate. Bis{μ-1,3-bis-[dimeth-yl(pyridin-3-yl)sil-yl]propane-κ2 N:N'}bis-[di-iodido-zinc(II)] from synchrotron data. [(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-methyl-3-propylimidazol-2-yl-idene-κC)iridium(I) tetra-fluorido-borate. Prop-2-enyl 6-amino-5-cyano-4-(4-iso-propylphen-yl)-2-methyl-4H-pyran-3-carboxyl-ate. Erratum: 2-(3-(4-Bromophenyl)-5-{3-[5-methyl-1-(4-methylphenyl)-1H-1,2,3-triazol-4-yl]-1-phenyl-1H-pyrazol-4-yl}-4,5-dihydro-1H-pyrazol-1-yl)-4-(4-chlorophenyl)-1,3-thiazole. Corrigendum.
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