Qiping He, Wenxin Yan, Xianglin Yu, Xinxiang Huang, Chang Liu, Yinchun Jiao, Yi Jin
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引用次数: 0
Abstract
Herein, we report a applicable method for metal-catalyzed para-Csp2−H functionalization of arylamines through photoinduced ligand-to-metal charge transfer (LMCT). The Photo-LMCT-homolysis mode allows Sc−N complexes to form nitrogen radical intermediates, which are then isomerized into aryl radicals and prepared for subsequent radical coupling. A selective construction of C−O, C−S, C−Se, and C−C bonds has been achieved, and these reactions offer operationally simple, low-catalyst, and highly regioselective procedures for accessing valuable arylamine functionalization in a single step.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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