Chang-Qing Qin, Xin-Ni Liu, Man-Zhen Gu, Yi-Bing Xu, Guo-Shu Chen and Yun-Lin Liu
{"title":"DBU-mediated synthesis of amides from carbodiimides and unstrained 1,3-diketones†","authors":"Chang-Qing Qin, Xin-Ni Liu, Man-Zhen Gu, Yi-Bing Xu, Guo-Shu Chen and Yun-Lin Liu","doi":"10.1039/D4NJ04537H","DOIUrl":null,"url":null,"abstract":"<p >A DBU-mediated synthesis of amides by using the readily available carbodiimides as nitrogen sources and unstrained 1,3-ketones as acyl sources has been developed. This reaction proceeds through the cleavage of two C<img>N bonds of the carbodiimides, two C(CO)–C bonds of 1,3-diketones and the formation of two new C(CO)–N bonds, simultaneously.</p>","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":" 2","pages":" 366-370"},"PeriodicalIF":2.7000,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/nj/d4nj04537h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A DBU-mediated synthesis of amides by using the readily available carbodiimides as nitrogen sources and unstrained 1,3-ketones as acyl sources has been developed. This reaction proceeds through the cleavage of two CN bonds of the carbodiimides, two C(CO)–C bonds of 1,3-diketones and the formation of two new C(CO)–N bonds, simultaneously.
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