Correlation of the catalytic performance with Ruδ+ species on Ru/Nb2O5 in furfural aqueous reductive conversion†

IF 4.4 3区 化学 Q2 CHEMISTRY, PHYSICAL Catalysis Science & Technology Pub Date : 2024-12-02 DOI:10.1039/D4CY01272K
Yulong Deng, Binyu Zhang, Huiru Wu, Zhuo He, Xiaorui Du, Jiayi Ou, Tianyu Ren, Haiyong Wang, Yuhe Liao, Qiying Liu, Chenguang Wang and Yanbin Cui
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Abstract

Ru/Nb2O5 is effective for furfural aqueous reductive conversion. Systematic characterization, kinetic studies and in situ DRIFT tests demonstrated that the Ruδ+ species abundance is highly correlated with the adsorption behavior of the substrate, key intermediate and product (furfural, 2-cyclopentenone, and cyclopentanone), which governs the FFR conversion rate and cyclopentanoid product selectivity.

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来源期刊
Catalysis Science & Technology
Catalysis Science & Technology CHEMISTRY, PHYSICAL-
CiteScore
8.70
自引率
6.00%
发文量
587
审稿时长
1.5 months
期刊介绍: A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days
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