Correlation of the catalytic performance with Ruδ+ species on Ru/Nb2O5 in furfural aqueous reductive conversion†

IF 4.2 3区 化学 Q2 CHEMISTRY, PHYSICAL Catalysis Science & Technology Pub Date : 2024-11-07 Epub Date: 2024-12-02 DOI:10.1039/d4cy01272k
Yulong Deng , Binyu Zhang , Huiru Wu , Zhuo He , Xiaorui Du , Jiayi Ou , Tianyu Ren , Haiyong Wang , Yuhe Liao , Qiying Liu , Chenguang Wang , Yanbin Cui
{"title":"Correlation of the catalytic performance with Ruδ+ species on Ru/Nb2O5 in furfural aqueous reductive conversion†","authors":"Yulong Deng ,&nbsp;Binyu Zhang ,&nbsp;Huiru Wu ,&nbsp;Zhuo He ,&nbsp;Xiaorui Du ,&nbsp;Jiayi Ou ,&nbsp;Tianyu Ren ,&nbsp;Haiyong Wang ,&nbsp;Yuhe Liao ,&nbsp;Qiying Liu ,&nbsp;Chenguang Wang ,&nbsp;Yanbin Cui","doi":"10.1039/d4cy01272k","DOIUrl":null,"url":null,"abstract":"<div><div>Ru/Nb<sub>2</sub>O<sub>5</sub> is effective for furfural aqueous reductive conversion. Systematic characterization, kinetic studies and <em>in situ</em> DRIFT tests demonstrated that the Ru<sup><em>δ</em>+</sup> species abundance is highly correlated with the adsorption behavior of the substrate, key intermediate and product (furfural, 2-cyclopentenone, and cyclopentanone), which governs the FFR conversion rate and cyclopentanoid product selectivity.</div></div>","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":"15 1","pages":"Pages 33-40"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cy/d4cy01272k?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324006282","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/12/2 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Ru/Nb2O5 is effective for furfural aqueous reductive conversion. Systematic characterization, kinetic studies and in situ DRIFT tests demonstrated that the Ruδ+ species abundance is highly correlated with the adsorption behavior of the substrate, key intermediate and product (furfural, 2-cyclopentenone, and cyclopentanone), which governs the FFR conversion rate and cyclopentanoid product selectivity.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Ru/Nb2O5在糠醛水溶液还原转化中的催化性能与Ruδ+种类的关系
Ru/Nb2O5对糠醛的水还原转化有较好的效果。系统表征、动力学研究和原位漂移实验表明,钌+的丰度与底物、关键中间体和产物(糠醛、2-环戊酮和环戊酮)的吸附行为高度相关,从而决定了FFR的转化率和类环戊酮的选择性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Catalysis Science & Technology
Catalysis Science & Technology CHEMISTRY, PHYSICAL-
CiteScore
8.70
自引率
6.00%
发文量
587
审稿时长
1.5 months
期刊介绍: A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days
期刊最新文献
Antifluorite-derived Li7MnN4: revisiting the crystal structure and catalysis in ammonia decomposition. Cryogenic electron tomography reveals the mesoporous structure evolution during γ-Al2O3 supported Mo and MoNiP catalyst formation. Correction: Flow bioprocessing of citrus glycosides for high-value aglycone preparation Polystyrene-bound thioxanthone – a heterogeneous photocatalyst for alcohol oxidation via singlet oxygen production Manganese-enhanced cobalt catalysts for Fischer–Tropsch synthesis: a review of structural and electronic promotion effects
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1