Jeffrey Ash, Kevin Curtis, Shishir Bhowmik, Samuel O. Odoh, Jun Yong Kang
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引用次数: 0
Abstract
A hydropersulfide-mediated hydrothiolation reaction of alkenes has been developed for C–S bond formation with Markovnikov selectivity. This new approach is a transition-metal-, additive-, and solvent-free reaction under mild conditions. The reaction is postulated to proceed by an ionic mechanism with the release of elemental sulfur based on our control experiments and density functional theory calculations.
期刊介绍：
Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
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