Recent progress on photoactive nonprecious transition-metal complexes

IF 10.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Science China Chemistry Pub Date : 2024-11-15 DOI:10.1007/s11426-024-2345-0

Zhong-Liang Gong, Hong-Jie Zhang, Yan Cheng, Jianxun Liu, Yuhan Ai, Yaqin Li, Zhihui Feng, Qiong Zhang, Shaolong Gong, Yong Chen, Chang-Jiang Yao, Yuan-Yuan Zhu, Liang-Jin Xu, Yu-Wu Zhong

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Abstract

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

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光活性非贵重过渡金属配合物的研究进展

非贵重过渡金属的光活性配合物，主要包括元素周期表第一行和部分第二行，由于其低成本和长期可持续性而受到越来越多的关注。它们被认为是贵重过渡金属络合物同族物的有前途的替代品，在光电器件、人工光合作用、光催化、生物诊断和治疗等方面得到了广泛的研究。本文综述了光活性非贵重过渡金属配合物的经典和最新研究进展，包括光活性Zr、V、Cr、Mo和W配合物、Mn配合物和杂化物、Fe、Co、Ni和Cu配合物以及Zn和Cd配合物和杂化物。特别着重于分子设计，光物理和光化学性质的调制，以及代表性和最新开发的非贵金属配合物的应用。最后，对该领域的未来发展进行了展望。

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来源期刊

Science China Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

14.40

自引率

7.30%

发文量

3787

审稿时长

2.2 months

期刊介绍： Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field. Categories of articles include: Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry. Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies. Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.