{"title":"Bottleable triplet nitrenes","authors":"Dominik Munz","doi":"10.1038/s41557-024-01700-z","DOIUrl":null,"url":null,"abstract":"Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.","PeriodicalId":18909,"journal":{"name":"Nature chemistry","volume":"13 1","pages":""},"PeriodicalIF":19.2000,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1038/s41557-024-01700-z","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
Nitrenes are compounds featuring a monovalent nitrogen atom, and they are typically formed as transient intermediates in organic synthesis. They have been the subject of matrix studies for decades, but their stabilization remains challenging. Now, two independent works report the isolation of triplet arylnitrenes stabilized by a sterically encumbered substituent.
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