{"title":"Deciphering pH Mismatching at the Electrified Electrode–Electrolyte Interface towards Understanding Intrinsic Water Molecule Oxidation Kinetics","authors":"Miao Wang, Ken Sakaushi","doi":"10.1002/anie.202419823","DOIUrl":null,"url":null,"abstract":"By integrating operando electrochemical methods with (micro)kinetic modelling, the dynamic local pH effect for the oxygen evolution reaction is clarified. An unconventional reversible hydrogen reference electrode is employed, enabling a clearer interpretation of intrinsic electrochemical kinetics. This approach offers deeper insights into the microscopic electrode processes in the electrified electrode-electrolyte interface with dynamic local pH.","PeriodicalId":125,"journal":{"name":"Angewandte Chemie International Edition","volume":"80 1","pages":""},"PeriodicalIF":16.1000,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie International Edition","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/anie.202419823","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
By integrating operando electrochemical methods with (micro)kinetic modelling, the dynamic local pH effect for the oxygen evolution reaction is clarified. An unconventional reversible hydrogen reference electrode is employed, enabling a clearer interpretation of intrinsic electrochemical kinetics. This approach offers deeper insights into the microscopic electrode processes in the electrified electrode-electrolyte interface with dynamic local pH.
期刊介绍：
Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
