Correction to “Solid-State Hydroxide Ion Conductivity in Silver(I) Oxide, Ag2O”

IF 7 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Chemistry of Materials Pub Date : 2025-01-10 DOI:10.1021/acs.chemmater.4c03525
Leanna Schulte, Shihan Qin, Wonil Jung, Christy George, Jarrett D. Dillenburger, Akshay Venkatesh, Muhammad K. Ishak, Nichole M. Wonderling, Sariah Marth, Heemin Park, Chulsung Bae, Andrew M. Rappe, Thomas E. Mallouk
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Abstract

In the description of doping by reactions (2) and (3) on p. 11455, both reactions were described as “oxidative.” Only reaction (3) represents oxidative doping. The product of reaction (2) was written as Ag2–x(HxO)(OH)x, but the correct formula is Ag2–xHxO. The formula weight, written as (231.74 – 91.86x) g/mol, is corrected to (231.74 – 106.8x) g/mol, and accordingly the lowering of the density at the x = 0.01 doping level by reaction (2) is corrected from 0.40% to 0.46%; the raising of the density by reaction (3) is corrected from 0.05% to 0.07%. In the description of the hydroxide conductivity mechanism on p. 11455, it was stated that both the single and tandem OH systems are diamagnetic. Figures S10–S13 show that the single OH system is paramagnetic, whereas the tandem OH system is diamagnetic. On p. 11456, it was stated that NMR chemical shifts were calculated from the structures shown in Figure S15. The correct figure number is S16. This article has not yet been cited by other publications.
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对“氧化银(I) Ag2O中固态氢氧化物离子电导率”的修正
在第11455页上对反应(2)和(3)掺杂的描述中,这两个反应都被描述为“氧化的”。只有反应(3)代表氧化掺杂。反应(2)的产物写成Ag2-x (HxO)(OH)x,但正确的分子式是Ag2-xHxO。公式重量(231.74 - 91.86x) g/mol,修正为(231.74 - 106.8x) g/mol,相应地,反应(2)在x = 0.01掺杂水平下的密度降低由0.40%修正为0.46%;通过反应(3)提高的密度由0.05%修正为0.07%。在第11455页对氢氧化物导电机理的描述中,指出了单羟基和串联羟基体系都是抗磁性的。图S10-S13表明,单个OH -体系是顺磁性的,而串联OH -体系是反磁性的。在第11456页,我们指出核磁共振化学位移是从图S15所示的结构中计算出来的。正确的数字是S16。这篇文章尚未被其他出版物引用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemistry of Materials
Chemistry of Materials 工程技术-材料科学:综合
CiteScore
14.10
自引率
5.80%
发文量
929
审稿时长
1.5 months
期刊介绍: The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.
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