High Mobility Emissive Organic Semiconductors for Optoelectronic Devices

IF 15.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Journal of the American Chemical Society Pub Date : 2025-01-10 DOI:10.1021/jacs.4c11208
Ziyi Xie, Dan Liu, Can Gao, Xiaotao Zhang, Huanli Dong, Wenping Hu
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Abstract

High mobility emissive organic semiconductors (HMEOSCs) are a kind of unique semiconducting material that simultaneously integrates high charge carrier mobility and strong emission features, which are not only crucial for overcoming the performance bottlenecks of current organic optoelectronic devices but also important for constructing high-density integrated devices/circuits for potential smart display technologies and electrically pumped organic lasers. However, the development of HMEOSCs is facing great challenges due to the mutually exclusive requirements of molecular structures and packing modes between high charge carrier mobility and strong solid-state emission. Encouragingly, considerable advances on HMEOSCs have been made with continuous efforts, and the successful integration of these two properties within individual organic semiconductors currently presents a promising research direction in organic electronics. Representative progress, including the molecular design of HMEOSCs, and the exploration of their applications in photoelectric conversion devices and electroluminescent devices, especially organic photovoltaic cells, organic light-emitting diodes, and organic light-emitting transistors, are summarized in a timely manner. The current challenges of developing HMEOSCs and their potential applications in other related devices including electrically pumped organic lasers, spin organic light-emitting transistors are also discussed. We hope that this perspective will boost the rapid development of HMEOSCs with a new mechanism understanding and their wide applications in different fields entering a new stage.

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光电器件用高迁移率发光有机半导体
高迁移率发射有机半导体(HMEOSCs)是一种集高载流子迁移率和强发射特性于一体的独特半导体材料,它不仅对克服现有有机光电器件的性能瓶颈至关重要,而且对于构建高密度集成器件/电路以及潜在的智能显示技术和电泵浦有机激光器具有重要意义。然而,由于高载流子迁移率和强固态发射对分子结构和包装方式的要求相互排斥,hmeosc的发展面临着巨大的挑战。令人鼓舞的是,在不断的努力下,hmeosc已经取得了相当大的进展,并且在单个有机半导体中成功地集成了这两种特性,目前是有机电子学中一个很有前途的研究方向。及时总结了hmeosc的分子设计及其在光电转换器件和电致发光器件,特别是有机光伏电池、有机发光二极管和有机发光晶体管中的应用探索等具有代表性的进展。讨论了hmeosc在电抽运有机激光器、自旋有机发光晶体管等相关器件中的应用前景。我们希望这一视角将推动hmeosc的快速发展,对其机理有新的认识,在不同领域的广泛应用进入一个新的阶段。
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来源期刊
CiteScore
24.40
自引率
6.00%
发文量
2398
审稿时长
1.6 months
期刊介绍: The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.
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