Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction

IF 6.8 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Science China Materials Pub Date : 2024-11-08 DOI:10.1007/s40843-024-3165-6

Chao Li (, ), Hong Yan (, ), Hanlu Yang (, ), Wenqian Zhou (, ), Chengyu Xie (, ), Baocai Pan (, ), Qichun Zhang (, )

{"title":"Recent advances and future perspectives of metal-organic frameworks as efficient electrocatalysts for CO2 reduction","authors":"Chao Li \n (, ), Hong Yan \n (, ), Hanlu Yang \n (, ), Wenqian Zhou \n (, ), Chengyu Xie \n (, ), Baocai Pan \n (, ), Qichun Zhang \n (, )","doi":"10.1007/s40843-024-3165-6","DOIUrl":null,"url":null,"abstract":"<div><p>The conversion of carbon dioxide (CO<sub>2</sub>) to the reduced chemical compounds offers substantial environmental benefits through minimizing the emission of greenhouse gas and fostering sustainable practices. Recently, the unique properties of metal-organic frameworks (MOFs) make them attractive candidates for electrocatalytic CO<sub>2</sub> reduction reaction (CO<sub>2</sub>RR), providing many opportunities to develop efficient, selective, and environmentally sustainable processes for mitigating CO<sub>2</sub> emissions and utilizing CO<sub>2</sub> as a valuable raw material for the synthesis of fuels and chemicals. Here, the recent advances in MOFs as efficient catalysts for electrocatalytic CO<sub>2</sub>RR are summarized. The detailed characteristics, electrocatalytic mechanisms, and practical approaches for improving the electrocatalytic efficiency, selectivity, and durability of MOFs under realistic reaction conditions are also clarified. Furthermore, the outlooks on the prospects of MOF-based electrocatalysts in CO<sub>2</sub>RR are provided.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 1","pages":"21 - 38"},"PeriodicalIF":6.8000,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40843-024-3165-6.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s40843-024-3165-6","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

The conversion of carbon dioxide (CO₂) to the reduced chemical compounds offers substantial environmental benefits through minimizing the emission of greenhouse gas and fostering sustainable practices. Recently, the unique properties of metal-organic frameworks (MOFs) make them attractive candidates for electrocatalytic CO₂ reduction reaction (CO₂RR), providing many opportunities to develop efficient, selective, and environmentally sustainable processes for mitigating CO₂ emissions and utilizing CO₂ as a valuable raw material for the synthesis of fuels and chemicals. Here, the recent advances in MOFs as efficient catalysts for electrocatalytic CO₂RR are summarized. The detailed characteristics, electrocatalytic mechanisms, and practical approaches for improving the electrocatalytic efficiency, selectivity, and durability of MOFs under realistic reaction conditions are also clarified. Furthermore, the outlooks on the prospects of MOF-based electrocatalysts in CO₂RR are provided.

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Science China Materials Materials Science-General Materials Science

CiteScore

11.40

自引率

7.40%

发文量

949

期刊介绍： Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.